A Novel Route to Glass Fiber‐Reinforced Epoxy Matrix Composites: Visible Light Activated Radical Induced Cationic Frontal Polymerization
Yazarlar (3)
Cenk Kurtuluş Yalova Üniversitesi, Türkiye
Prof. Dr. Mustafa Çiftçi Bursa Teknik Üniversitesi, Türkiye
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | MACROMOLECULAR CHEMISTRY AND PHYSICS (Q2) | ||
| Dergi ISSN | 1022-1352 Dergi Bilgileri (2024) | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | Türkçe | Basım Tarihi | 07-2024 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 31-07-2024 |
| Cilt / Sayı / Sayfa | 226 / 7 / – | DOI | 10.1002/macp.202400080 |
| Makale Linki | https://doi.org/10.1002/macp.202400080 | ||
| UAK Araştırma Alanları |
Polimerik Malzemeler
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| Özet |
| In the current study, a novel radical-induced cationic frontal polymerization (RICFP) concept capable of rapid curing at room temperature via visible light irradiation is represented. Initially, the optimal formulation, which can be most effectively cured with visible light irradiation, is determined based on thickness, hardness, curing speed, and mechanical properties using FT-IR, DSC, TGA, and flexural test methods. Subsequently, the viability of the method is illustrated by fabricating glass fiber-reinforced composites through the hand lay-up technique, employing the optimized formulation and glass fibers in various forms (chopped strand mat and biaxial). Mechanical properties of the obtained composites, including bending, tensile, and shear tests, are carried out according to relevant international standards and compared with reference composites thermally cured with amine-based hardener by conventional method. A novel visible light curable epoxy resin for glass fiber-reinforced composites is developed, combining industrial-grade epoxy resin with a photoinitiator, photosensitizer, reactive solvent, and thermal initiator. Optimal formulation is identified by evaluating thickness, hardness, curing speed, and mechanical properties. The composites produced show mechanical properties comparable to thermally cured ones. image |
| Anahtar Kelimeler |
| composites | epoxides | glass fibers | photoinitiator | photopolymerization |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 6 |