In situ preparation of thermoset/clay nanocomposites via thiol-epoxy click chemistry
Yazarlar (4)
Ozlem Purut Koç
Yalova Üniversitesi
Yalova Üniversitesi
Dr. Öğr. Üyesi Seda BEKİN AÇAR Yalova Üniversitesi, Türkiye
Tamer Uyar
İhsan Doğramacı Bilkent Üniversitesi, Türkiye
İhsan Doğramacı Bilkent Üniversitesi, Türkiye
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
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| Dergi Adı | POLYMER BULLETIN (Q2) | ||
| Dergi ISSN | 0170-0839 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 11-2018 |
| Kabul Tarihi | 05-03-2018 | Yayınlanma Tarihi | 08-03-2018 |
| Cilt / Sayı / Sayfa | 75 / 11 / 4901–4911 | DOI | 10.1007/s00289-018-2306-1 |
| Makale Linki | http://link.springer.com/10.1007/s00289-018-2306-1 | ||
| Özet |
| A series of thermoset/clay nanocomposites are prepared by thiol-epoxy click reaction using commercially available starting compounds at ambient conditions in very good yields. The incorporation and exfoliation of clay nanolayers in the thermoset matrix are confirmed by FT-IR, XRD and TEM analyses. The influence of clay loadings on the thermal and mechanical analyses is investigated and all nanocomposites exhibit improved properties than that of the pristine thermoset. The nanocomposite containing 1% montmorillonite by weight has the most improved mechanical properties due to its highly exfoliated structure resulting in efficient interactions between clay and polymer matrix. A further increase of the clay loading results in the aggregation of clay plates to form intercalated structures leading to deteriorated thermal and mechanical properties of nanocomposites. |
| Anahtar Kelimeler |
| Click chemistry | Nanocomposites | Nanoclay | Thermoset | Thiol-epoxy reaction |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları |