Polyhedral oligomeric silsesquioxane-based hybrid networks obtained via thiol-epoxy click chemistry
Yazarlar (4)
Dr. Öğr. Üyesi Seda BEKİN AÇAR Yalova Üniversitesi, Türkiye
Mustafa Özçelik Yalova Üniversitesi, Türkiye
Tamer Uyar
İhsan Doğramacı Bilkent Üniversitesi, Türkiye
İhsan Doğramacı Bilkent Üniversitesi, Türkiye
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Iranian Polymer Journal English Edition (Q3) | ||
| Dergi ISSN | 1026-1265 Dergi Bilgileri (2017) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 06-2017 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 02-05-2017 |
| Cilt / Sayı / Sayfa | 26 / 6 / 405–411 | DOI | 10.1007/s13726-017-0529-x |
| Makale Linki | http://link.springer.com/10.1007/s13726-017-0529-x | ||
| UAK Araştırma Alanları |
Polimer Bilimi ve Teknolojileri
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| Özet |
| A series of hybrid networks based on polyhedral oligomeric silsesquioxane (POSS) were prepared by thiol-epoxy click reaction using commercially available octakis-glycidyl-POSS (G-POSS), trimethylolpropane triglycidyl ether, and trimethylolpropane tris(3-mercaptopropionate) as monomers. The click reaction was simply catalyzed by lithium hydroxide which proceeded readily at ambient conditions in very good yields. The incorporation of G-POSS into the network was clearly determined by transmission electron microscopy, FTIR, and 1H-NMR spectroscopy techniques performed with a model study using 1-butane thiol and G-POSS molecules. The homogeneous distribution of G-POSS up to 5 wt% in the hybrid network was apparently confirmed by morphological investigations. By increasing G-POSS content higher than 5 wt%, the heterogeneous dispersion of G-POSS was determined from the tensile strength … |
| Anahtar Kelimeler |
| Click chemistry | Hybrid networks | Polyhedral oligomeric silsesquioxanes | Thermosets | Thiol-epoxy reaction |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Yöksis | 1 |
| Web of Science | 18 |
| Scopus | 18 |
| Google Scholar | 18 |