Orthogonal synthesis and modification of hyperbranched polymers via different colors of light
Yazarlar (3)
Esra Kökçü
Yalova Üniversitesi, Türkiye
Prof. Dr. Mustafa Çiftçi Bursa Teknik Üniversitesi, Türkiye
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Polymer Science (Q1)
Dergi ISSN 2642-4150 Dergi Bilgileri (2024)
Dergi Tarandığı Indeksler SCI
Makale Dili Türkçe Basım Tarihi 02-2024
Kabul Tarihi 10-02-2024 Yayınlanma Tarihi 21-02-2024
Cilt / Sayı / Sayfa 62 / 10 / 2094–2102 DOI 10.1002/pol.20240005
Makale Linki https://doi.org/10.1002/pol.20240005
UAK Araştırma Alanları
Polimer Bilimi
Özet
A versatile and straightforward approach for the synthesis of functional hyperbranched polymers with tunable properties is represented utilizing a chromatic orthogonal protocol. The method involves the combination of photo‐induced electron/energy transfer‐reversible addition‐fragmentation chain transfer (PET‐RAFT) and self‐condensing vinyl polymerization (SCVP) under visible light irradiation leading to the formation of hyperbranched polymers with well‐defined properties possessing photo‐caged diene moieties. Upon UV light irradiation, the remaining photoenol functionality was efficiently activated for the post‐functionalization of the synthesized hyperbranched polymers with maleimide functional molecules via Diels‐Alder photo‐click chemistry. Both low molar mass and polymeric maleimide functional click components, namely N‐phenylmaleimide, poly(ethylene glycol)‐maleimide and polycaprolactone …
Anahtar Kelimeler
chromatic orthogonality | click chemistry | hyperbranched polymers | photopolymerization
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Scopus 1
Google Scholar 1
Orthogonal synthesis and modification of hyperbranched polymers via different colors of light