Synthesis of cinacalcet containing acrylamide hydrogels by photopolymerization and studying their sensing properties
Yazarlar (3)
Erdinç Doğancı Kocaeli Üniversitesi, Türkiye
Mustafa Uygun
Gebze Teknik Üniversitesi, Türkiye
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Iranian Polymer Journal English Edition (Q2)
Dergi ISSN 1026-1265 Dergi Bilgileri (2023)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili Türkçe Basım Tarihi 09-2023
Kabul Tarihi 28-05-2023 Yayınlanma Tarihi 09-09-2023
Cilt / Sayı / Sayfa 32 / 11 / 1359–1366 DOI 10.1007/s13726-023-01200-w
Makale Linki http://dx.doi.org/10.1007/s13726-023-01200-w
UAK Araştırma Alanları
Polimer Bilimi Nanoteknoloji Yüzey Kimyası
Özet
Novel cinacalcet containing acrylamide hydrogel (CIN-gel) was fabricated by free radical photopolymerization of acrylamide/N,N’-methylenebisacrylamide with cinacalcet hydrochloride as a photoinitiator. This hydrogel prepared by a one-pot photo-induced polymerization system was characterized with respect to its morphological and fluorescence features by means of SEM, UV–vis, and fluorescence spectroscopy. The CIN-gel displayed dual fluorescence emission when excited at 250 nm in water:acetonitrile (1:1, w/w) solution system owing to twisted intramolecular charge transfer between naphthalene and dimethylamino units in the cinacalcet moiety. The prepared fluorophore containing CIN-gel was employed as a fluorescent probe towards certain specific heavy metal ions (HMIs) such as Pb2+, Sn2+, Zn2+ and nitroaromatic compounds (NACs) such as 2-nitrotoluene, 2,4-dinitrophenol, 1,2-dinitrobenzene, 2,4 …
Anahtar Kelimeler
Cinacalcet hydrochloride | Heavy metal ion-sensing | Hydrogel | Nitroaromatic compound | Photoinitiation