The effect of POSS nanoparticles on crosslinking of styrene-butadiene rubber nanocomposites
Yazarlar (3)
Dr. Öğr. Üyesi Seda BEKİN AÇAR Yalova Üniversitesi, Türkiye
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
Prof. Dr. Bağdagül Karaağaç Kocaeli Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Turkish Journal of Chemistry (Q3) | ||
| Dergi ISSN | 1300-0527 Dergi Bilgileri (2023) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2023 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-01-2023 |
| Cilt / Sayı / Sayfa | 47 / 2 / 417–425 | DOI | 10.55730/1300-0527.3548 |
| Makale Linki | http://dx.doi.org/10.55730/1300-0527.3548 | ||
| UAK Araştırma Alanları |
Polimer Bilimi
Nanoteknoloji
Yüzey Kimyası
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| Özet |
| The effect of octaisobutyl-polyhedral oligomeric silsesquioxane (OIB-POSS) as a nanosized reinforcement on the cure kinetics, crosslinking density, and mechanical properties of styrene-butadiene rubber (SBR) nanocomposites was examined in this study. For this purpose, SBR compounds with various OIB-POSS nanoparticle loadings at 1, 3, and 5 phr were prepared and their results were compared with a reference compound without OIB-POSS. When 1 phr of OIB-POSS was added to the rubber matrix, the elongation at break values and tensile strength of the corresponding nanocomposite increased by 24.1% and 29.2% compared to the reference sample, respectively. The presence of OIB-POSS nanoparticles and their random distribution in the SBR matrix was confirmed by transmission electron microscopy. The crosslinking density of nanocomposites was calculated by the Flory-Rehner method and a decrease was observed with the addition of OIB-POSS nanoparticles. In addition, thermal aging process as 70 C for 70 h was applied to vulcanized samples. It was noted that the mechanical properties of SBR/OIB-POSS nanocomposites remarkably improved, whereas their crosslinking densities gradually decreased after thermal aging. |
| Anahtar Kelimeler |
| Nanocomposites | nanoparticles | polyhedral oligomeric silsesquioxane | rubber | styrene-butadiene rubber |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Scopus | 8 |
| Google Scholar | 10 |
| TR Dizin | 3 |
| PubMed | 1 |