Covalent modification of poly(vinyl chloride) via organometallic Barbier reaction
Yazarlar (3)
Rabia Arslan
Doç. Dr. Mehmet ARSLAN Yalova Üniversitesi, Türkiye
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Elsevier BV (Q1) | ||
| Dergi ISSN | 0014-3057 Dergi Bilgileri (2022) | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | Türkçe | Basım Tarihi | 08-2022 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-08-2022 |
| Cilt / Sayı / Sayfa | 177 / 0 / 111475–111475 | DOI | 10.1016/j.eurpolymj.2022.111475 |
| Makale Linki | http://dx.doi.org/10.1016/j.eurpolymj.2022.111475 | ||
| UAK Araştırma Alanları |
Polimer Bilimi
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| Özet |
| The development of efficient synthetic methodologies for chemical functionalization and modification of existing polymers to improve or diversify the physicochemical and mechanical properties is an ongoing quest in macromolecular science. This is especially true for the generation of polymeric materials out of commercial/commodity polymers via structural tailoring since these polymers are produced in vast quantities and are structurally diverse. In this study, we report on benign chemical modification of an important commercial polymer, poly(vinyl chloride) (PVC) via Barbier reaction. The methodology is based on the employment of magnesium metal to generate nucleophilic alkyl-magnesium chloride groups on polymer backbone and addition of these nucleophilic centers to electrophilic carbonyl groups. The synthetic procedure can be implemented in a one-pot fashion by utilizing commonly available aldehyde or … |
| Anahtar Kelimeler |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Google Scholar | 7 |