Facile UV-induced covalent modification and crosslinking of styrene\isoprene\styrene copolymer via Paterno\Büchi [2 + 2] photocycloaddition
Yazarlar (4)
Doç. Dr. Mehmet ARSLAN Yalova Üniversitesi, Türkiye
Öğr. Gör. Dr. Özgür CEYLAN Yalova Üniversitesi, Türkiye
Rabia Arslan
Yalova Üniversitesi, Türkiye
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Rsc Advances (Q2)
Dergi ISSN 2046-2069 Dergi Bilgileri (2021)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 03-2021
Kabul Tarihi – Yayınlanma Tarihi 01-01-2021
Cilt / Sayı / Sayfa 11 / 15 / 8585–8593 DOI 10.1039/d1ra00033k
Makale Linki http://dx.doi.org/10.1039/d1ra00033k
UAK Araştırma Alanları
Polimer Bilimi Nanoteknoloji Yüzey Kimyası
Özet
The chemical functionalization or modification of polymers to alter or improve the physical and mechanical properties constitutes an important field in macromolecular research. Fabrication of polymeric materials via structural tailoring of commercial or commodity polymers that are produced in vast quantities especially possess unique advantages in material applications. In the present study, we report on benign chemical modification of unsaturated styrene–isoprene–styrene (SIS) copolymer using available backbone alkene groups. Covalent attachment of aldehyde functional substrates onto reactive isoprene double bond residues was conveniently carried out using UV-induced Paterno–Büchi [2 + 2] cycloaddition. Model organic compounds with different structures were utilized in high efficiency chemical modification of parent polymer chains via oxetane ring formation. Functionalization studies were confirmed via1 …
Anahtar Kelimeler
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Web of Science 12
Scopus 14
Google Scholar 16
PubMed 2
Facile UV-induced covalent modification and crosslinking of styrene\isoprene\styrene copolymer via Paterno\Büchi [2 + 2] photocycloaddition