Synthesis, characterization and surfactant properties of cholic acid containing linear and star polymers
Yazarlar (3)
Prof. Dr. Erdinc Doganci Kocaeli Üniversitesi, Türkiye
Ahmet Uner
Gebze Teknik Üniversitesi, Türkiye
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Polymer Research (Q2)
Dergi ISSN 1022-9760 Dergi Bilgileri (2021)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili Türkçe Basım Tarihi 01-2021
Kabul Tarihi 06-05-2021 Yayınlanma Tarihi 08-06-2021
Cilt / Sayı / Sayfa 28 / 7 / – DOI 10.1007/s10965-021-02564-4
Makale Linki http://dx.doi.org/10.1007/s10965-021-02564-4
UAK Araştırma Alanları
Polimer Bilimi Nanoteknoloji Yüzey Kimyası
Özet
Surface-active linear and star-shaped miktoarm polymers containing cholic acid as a bile acid derivative are prepared by esterification of poly(ethylene glycol methyl ether) and subsequent ring-opening polymerization of epsilon caprolactone, respectively. The chemical structures, molecular characteristics and thermal properties of obtained polymers are clearly confirmed by FT-IR, 1H-NMR, GPC, DSC and TGA analysis. The presence of characteristic bands of cholic acid, ether and ester groups in FT-IR and 1H-NMR spectroscopies is proof of the successful synthesis of linear and star-shaped polymers. The melting point of star-shaped polymer is slightly lower than the linear polymer. Additionally, their surface activity properties have been investigated by AFM, SEM and contact angle studies and it is found that they can be self-assembled into micelles. Furthermore, the size of the micelles and contact angle …
Anahtar Kelimeler
Bile acids | Polymer micelles | Polymeric surfactants | Star polymer | Surface tension
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Scopus 4
Google Scholar 4
Synthesis, characterization and surfactant properties of cholic acid containing linear and star polymers