Methacrylate-functionalized POSS influence on cross-linking and mechanical properties of styrene-butadiene rubber
Yazarlar (3)
Dr. Öğr. Üyesi Seda BEKİN AÇAR Yalova Üniversitesi, Türkiye
Bağdagül Karaağaç Kocaeli University, Türkiye
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
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| Dergi Adı | Iranian Polymer Journal (Q3) | ||
| Dergi ISSN | 1026-1265 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2021 |
| Kabul Tarihi | 14-04-2021 | Yayınlanma Tarihi | 22-04-2021 |
| Cilt / Sayı / Sayfa | 30 / 7 / 697–705 | DOI | 10.1007/s13726-021-00924-x |
| Makale Linki | http://dx.doi.org/10.1007/s13726-021-00924-x | ||
| Özet |
| The addition of methacrylate-functional polyhedral oligomeric silsesquioxane (MA-POSS) nanoparticles to styrene-butadiene rubber (SBR) composites was evaluated in terms of rheological, mechanical, and morphological properties. The aging process and cross-link density of rubber nanocomposites were examined in presence of MA-POSS. The MA-POSS could directly participate in the vulcanization reaction due to its methacrylate groups and its concentration affected the rheological and mechanical properties of rubber. The sulfur vulcanization characteristics of MA-POSS/SBR nanocomposites were determined by moving die rheometer. It was indicated that the addition of MA-POSS to SBR composites retarded the curing time and decreased the cross-link density. Due to an effective interaction between MA-POSS nanofiller and SBR matrix and excellent dispersion of POSS, the mechanical properties of nanocomposites were higher than those of the reference compound without MA-POSS. However, there was no significant change investigated in tensile retention in presence of MA-POSS. The presence and the random distribution of MA-POSS in SBR matrix was confirmed by TEM analysis. The cross-link densities of the composites, which were calculated using Flory-Rehner equation, decreased with increasing amount of POSS nanofiller. It was finally revealed that the thermal aging dramatically reduced the mechanical properties and cross-link density of MA-POSS/SBR nanocomposites. |
| Anahtar Kelimeler |
| In situ polymerization | Nanocomposites | Polyhedral oligomeric silsesquioxane | Rubber | Styrene-butadiene copolymer |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları |