Photoinduced free radical promoted cationic polymerization 40 years after its discovery
Yazarlar (3)
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
Jacques Lalevée Universites de Strasbourg Etablissements Associes
Yusuf Yağcı Istanbul Technical University, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Polymer Chemistry
Dergi ISSN 1759-9954 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce Basım Tarihi 02-2020
Kabul Tarihi Yayınlanma Tarihi 01-01-2020
Cilt / Sayı / Sayfa 11 / 6 / 1111–1121 DOI 10.1039/c9py01903k
Makale Linki http://xlink.rsc.org/?DOI=C9PY01903K
Özet
This perspective article is prepared in the memory of Anthony Ledwith who discovered Free Radical Promoted Cationic Polymerization (FRPCP) as a versatile photoinitiating system for cationic polymerization about four decades ago. Mechanistically, distinct modes for the photochemical formation of electron donor radicals in the UV, Vis and NIR range that can be oxidized to reactive cations to initiate the cationic polymerization of oxiranes and vinyl monomers are discussed. The dual polymerization strategies that have been applied to combine FRPCP with the other modes of polymerization processes are presented.
Anahtar Kelimeler
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Photoinduced free radical promoted cationic polymerization 40 years after its discovery

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