Aliphatic polyester/polyhedral oligomeric silsesquioxanes hybrid networks via copper‐free 1,3‐dipolar cycloaddition click reaction
Yazarlar (4)
Dr. Öğr. Üyesi Reyhan Özdoğan Bursa Teknik Üniversitesi, Türkiye
Ozgun Daglar
Istanbul Technical University, Türkiye
Istanbul Technical University, Türkiye
Prof. Dr. Hakan Durmaz İstanbul Teknik Üniversitesi, Türkiye
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Polymer Science Part A Polymer Chemistry (Q1) | ||
| Dergi ISSN | 0887-624X Dergi Bilgileri (2019) | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 11-2019 |
| Kabul Tarihi | 05-09-2019 | Yayınlanma Tarihi | 30-09-2019 |
| Cilt / Sayı / Sayfa | 57 / 22 / 2222–2227 | DOI | 10.1002/pola.29507 |
| Makale Linki | https://onlinelibrary.wiley.com/doi/abs/10.1002/pola.29507 | ||
| UAK Araştırma Alanları |
Polimer Bilimi
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| Özet |
| In this study, we describe the preparation and characterization of a new class of thermoset hybrid networks containing aliphatic polyester and polyhedral oligomeric silsesquioxanes (POSS). The copper‐free 1,3‐dipolar cycloaddition click reaction of internal alkyne functionalized aliphatic polyester and multifunctional azido POSS with different concentrations led to highly crosslinked thermoset networks. The click reactions performed under ambient conditions (i.e., in tetrahydrofuran at room temperature for 1 day) in the absence of any catalyst. The chemical composition of hybrid networks and homogenous distribution of POSS molecules were confirmed by Fourier transform infrared spectroscopy and scanning electron microscopy with energy dispersive spectroscopy. The swelling ratios of hybrid networks were commonly decreased by increasing POSS‐N3 content and by changing polar solvents to apolar solvents … |
| Anahtar Kelimeler |
| click chemistry | hybrid networks | nanoparticles | networks and polyesters | polyester | polyhedral oligomeric silsesquioxanes | thermosets |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 22 |
| Scopus | 22 |
| Google Scholar | 25 |