Synthesis of fluorinated polypropylene using CuAAC click chemistry
Yazarlar (3)
G. Acik
Yalova Üniversitesi, Türkiye
Yalova Üniversitesi, Türkiye
C. Elif Cansoy
Pîrî Reis Üniversitesi, Türkiye
Pîrî Reis Üniversitesi, Türkiye
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Applied Polymer Science (Q2) | ||
| Dergi ISSN | 0021-8995 Dergi Bilgileri (2019) | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 02-2019 |
| Kabul Tarihi | 28-07-2018 | Yayınlanma Tarihi | 08-10-2018 |
| Cilt / Sayı / Sayfa | 136 / 7 / 47072–0 | DOI | 10.1002/app.47072 |
| Makale Linki | https://onlinelibrary.wiley.com/doi/abs/10.1002/app.47072 | ||
| UAK Araştırma Alanları |
Polimer Bilimi
|
||
| Özet |
| Synthesis of fluorine containing polypropylene (PPF) from chlorinated polypropylene (PPCl) via Cu(I) catalyzed Huisgen type 1,3‐dipolar cycloaddition (CuAAC) and its water repellency properties are demonstrated. Initially, clickable azido‐functional polypropylene (PPN3) and alkyne‐functionalized fluorine compound (FAl) are independently prepared by nucleophilic substitution of PPCl with azidotrimethylsilane‐tetrabutylammonium fluoride and esterification reactions of 2,2,3,3,4,4,5,5‐octafluoro‐1‐pentanol with 4‐pentyonic acid. The CuAAC reaction between PPN3 and FAl leads to corresponding PPF under mild conditions. The chemical structures and surface properties of desired PPF are characterized by Fourier transform infrared, 1H‐NMR, differential scanning calorimetry, scanning electron microscopy, atomic force microscope, and contact angle analyses. Based on water contact angle … |
| Anahtar Kelimeler |
| functionalization of polymers | polyolefins | surfaces and interfaces |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 27 |
| Scopus | 30 |
| Google Scholar | 32 |