Polypropylene-based graft copolymers via CuAAC click chemistry
Yazarlar (3)
G. Acik
Yalova Üniversitesi, Türkiye
Yalova Üniversitesi, Türkiye
E. Sey
Trakya Üniversitesi, Türkiye
Trakya Üniversitesi, Türkiye
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
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| Dergi Adı | Express Polymer Letters (Q1) | ||
| Dergi ISSN | 1788-618X Dergi Bilgileri (2018) | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2018 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-01-2018 |
| Cilt / Sayı / Sayfa | 12 / 5 / 418–428 | DOI | 10.3144/expresspolymlett.2018.35 |
| Makale Linki | http://www.expresspolymlett.com/letolt.php?file=EPL-0008822mi=c | ||
| UAK Araştırma Alanları |
Polimer Bilimi
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| Özet |
| Graft copolymers from commercial chlorinated polypropylene (PP-Cl) possessing either poly (ethylene glycol)(PEG) or poly (ɛ-caprolactone)(PCL) grafts are synthesized by copper (I)-catalyzed azide-alkyne cycloaddition ‘click’reaction (CuAAC). For this purpose, azido-functional polypropylene is prepared by nucleophilic substitution of chlorine groups of PP-Cl with azidotrimethylsilane-tetrabutylammonium fluoride. Whereas, the clickable alkyne end-functional PEG and PCL are independently synthesized by esterification reaction of poly (ethylene glycol) methyl ether with 4-pentyonic acid at room temperature and ring-opening polymerization of ε-caprolactone using stannous octoate as catalyst and propargyl alcohol as initiator. Finally, the corresponding graft copolymers, PP-g-PEG and PP-g-PCL, with different surface properties were successfully synthesized by CuAAC ‘click’reaction under mild condition. Spectral, chromatographic and thermal analyses at various stages prove the formation of desired polypropylene-based graft copolymers with well-defined properties. Furthermore, the water contact angle values of PP-Cl, PP-g-PEG and PP-g-PCL are found as 90±1, 78±1.8 and 83±2.1, respectively. |
| Anahtar Kelimeler |
| Chlorinated polypropylene | Copper (i)-catalyzed azide-alkyne cycloaddition | Graft copolymers | Polymer synthesis | Water contact angle |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Scopus | 28 |
| Google Scholar | 33 |