Hybrid film properties of the linseed oil based alkyd resin modified with glycidyl polyhedral oligomeric silsesquioxane
Yazarlar (4)
Sibel Sogukkanli
Istanbul Technical University
Doç. Dr. Mesut YILMAZOĞLU Yalova Üniversitesi, Türkiye
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
Ahmet Tuncer Erciyes
İstanbul Teknik Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı PROGRESS IN ORGANIC COATINGS
Dergi ISSN 0300-9440 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce Basım Tarihi 11-2018
Kabul Tarihi Yayınlanma Tarihi 01-11-2018
Cilt / Sayı / Sayfa 124 / 0 / 175–184 DOI 10.1016/j.porgcoat.2018.08.018
Makale Linki https://linkinghub.elsevier.com/retrieve/pii/S0300944017308767
Özet
A simple strategy was developed for the modification of linseed oil-based alkyd resin with glycidyl polyhedral oligomeric silsesquioxanes (GPOSS) to obtain a hybrid material. The incorporation of GPOSS into alkyd resin was done by simultaneous reactions between hydroxyl groups coming from ring-opened epoxides of GPOSS and partial glycerides and carboxylic acid groups of phthalic anhydride. The obtained hybrid material has significantly improved film properties and thermal stabilities compared to unmodified neat alkyd resin. Notably, the samples containing 5% GPOSS showed better film properties such as flexibility, adhesion, drying time, resistances to alkali, acid and water. Thus, this product can be used as an oil-based binder.
Anahtar Kelimeler
Alkyd resins | Film property | Glycerides | Hybrid materials | Linseed oil | Polyhedral oligomeric silsesquioxane