Antibacterial film from chlorinated polypropylene via CuAAC click chemistry
Yazarlar (4)
Gökhan Açık Piri Reis Üniversitesi, Türkiye
Çağatay Altınkök Trakya University
Hülya Ölmez
Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK)
Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK)
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
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| Dergi Adı | PROGRESS IN ORGANIC COATINGS | ||
| Dergi ISSN | 0300-9440 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 12-2018 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-12-2018 |
| Cilt / Sayı / Sayfa | 125 / 0 / 73–78 | DOI | 10.1016/j.porgcoat.2018.08.029 |
| Makale Linki | https://linkinghub.elsevier.com/retrieve/pii/S0300944018300031 | ||
| Özet |
| Polypropylene possessing quaternary ammonium salt (PP-QAS) is synthesized by copper (I)-catalyzed azide-alkyne cycloaddition "click" reaction (CuAAC) starting from chlorinated polypropylene (PP-Cl). The antibacterial properties of PP-QAS have been investigated on gram-positive (Staphylococcus aureus) and gram-negative (Escherichia colt) bacteria. For this purpose, clickable azide functionality has been introduced into PP-Cl backbone by using azidotrimethylsilane (TMS-N-3) - tetrabutylammonium fluoride solution (TBAF) system in tetrahydrofuran (THF) (PP-N-3). Independently clickable alkyne functionalized QAS is prepared by the reaction between 3-dimethylamino-1-propyne and benzyl bromide in the presence of triethyl amine (TEA). Finally, the polypropylene film containing quaternary ammonium salt (PP-QAS) is prepared by the successive CuAAC click reaction and solution casting method. The preparation of PP-QAS is monitored by fourier transform infrared (FT-IR) spectroscopy, proton nuclear magnetic resonance (H-1-NMR), differential scanning calorimetry (DSC) and scanning electron microscope (SEM) analyses at various stages. Based on antibacterial activity experiments, the PP-QAS coupons significantly inhibit both the growth of S. aureus and E. coli (p < 0.05) compared to neat PP-CI and control samples. |
| Anahtar Kelimeler |
| Antibacterial activity | Chlorinated polypropylene | Copper (I)-catalyzed azide-alkyne | cycloaddition | Polypropylene |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları |