Synthesis and Characterization of Polysulfone-based Graft Copolymer Possessing Quaternary Ammonium Salts via Photoiniferter Polymerization
Yazarlar (2)
Serhat Oran
Yalova Üniversitesi, Türkiye
Yalova Üniversitesi, Türkiye
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(Diğer hakemli uluslarası dergilerde yayınlanan tam makale)
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| Dergi Adı | Journal of the Turkish Chemical Society, Section A: Chemistry | ||
| Dergi ISSN | 2149-0120 | ||
| Dergi Tarandığı Indeksler | TR DİZİN | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2017 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 19-11-2017 |
| Cilt / Sayı / Sayfa | 5 / 1 / 117–132 | DOI | 10.18596/jotcsa.346590 |
| Makale Linki | http://dergipark.gov.tr/doi/10.18596/jotcsa.346590 | ||
| UAK Araştırma Alanları |
Polimer Bilimi
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| Özet |
| A well-defined polysulfone-based graft copolymerscontaining quaternary ammonioum salts are successfully prepared by photoinifertermethod under mild conditions. The corresponding macroiniferter agent issequentially synthesized by chloromethylation and nucleophilic substitutionreaction between obtained chloromethylated polysulfone and sodium diethyldithiocarbamate. Upon UV irradiation, this macroiniferter enables thesuccessful grafting of 2-(dimethylamino)ethyl methacrylate onto the polysulfonebackbone in a controlled manner. After the successful synthesis of graftcopolymers, the tertiary amine groups in the side-chains are readily quaternizedusing methyl iodide to get desired quaternary ammonioum salts containing graftcopolymers. |
| Anahtar Kelimeler |
| Graft copolymer | Iniferter | Photopolymerization | Polysulfone | Quarternary ammonium salts |
BM Sürdürülebilir Kalkınma Amaçları
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| Scopus | 3 |
| Google Scholar | 3 |