In-situ preparation of poly(2-ethyl-2-oxazoline)/clay nanocomposites via living cationic ring-opening polymerization
Yazarlar (5)
Dr. Öğr. Üyesi Umut Ugur Ozkose İstanbul Teknik Üniversitesi, Türkiye
Dr. Öğr. Üyesi Cagatay Altinkok Yalova Üniversitesi, Türkiye
Öğr. Gör. Ozgur Yilmaz Tubıtak Marmara Research Center, Türkiye
Doç. Dr. Onur Alptürk İstanbul Teknik Üniversitesi, Türkiye
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | European Polymer Journal (Q1) | ||
| Dergi ISSN | 0014-3057 Dergi Bilgileri (2017) | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 03-2017 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-03-2017 |
| Cilt / Sayı / Sayfa | 88 / 1 / 586–593 | DOI | 10.1016/j.eurpolymj.2016.07.004 |
| Makale Linki | http://linkinghub.elsevier.com/retrieve/pii/S0014305716301434 | ||
| UAK Araştırma Alanları |
Polimer Bilimi
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| Özet |
| The present study reports for the first time the preparation of poly(2-ethyl-2-oxazoline)/clay nanocomposites. The tosyl-functionalized montmorillonite clay is utilized as initiator for the living cationic ring-opening polymerization of 2-ethyl-2-oxazoline, which triggers the delamination of silicate layers in the polymer matrix and leading to nanocomposite formation. The living nature of the polymerization has been confirmed by kinetic studies. The morphology and thermal properties of nanocomposite have been evaluated using X-ray diffraction, transmission electron microscopy, differential scanning calorimeter and thermogravimetric analysis. All nanocomposite samples have a mixed exfoliated/intercalated silicate layers and an improved thermal stability compared to pure poly(2-ethyl-2-oxazoline). |
| Anahtar Kelimeler |
| Cationic ring-opening polymerization | Living polymerization | Nanocomposites | Organoclay | Polyoxazolines |
Science Direct
In-situ preparation of poly(2-ethyl-2-oxazoline)/clay nanocomposites via living cationic ring-opening polymerization
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Yöksis | 1 |
| Scopus | 47 |
| Google Scholar | 59 |