Preparation of fluorinated methacrylate/clay nanocomposite via iin-situ polymerization: Characterization, structure, and properties/title
Yazarlar (7)
Mohamed Karamane
Cadi Ayyad University, Fas
Cadi Ayyad University, Fas
Mustapha Raihane
Cadi Ayyad University, Fas
Cadi Ayyad University, Fas
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
Tamer Uyar
İhsan Doğramacı Bilkent Üniversitesi, Türkiye
İhsan Doğramacı Bilkent Üniversitesi, Türkiye
Mohamed Lahcini
Cadi Ayyad University, Fas
Cadi Ayyad University, Fas
Mohamed Ilsouk
Cadi Ayyad University, Fas
Cadi Ayyad University, Fas
Öğr. Gör. Yusuf Yağcı İstanbul Teknik Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Polymer Science Part A Polymer Chemistry (Q1) | ||
| Dergi ISSN | 0887-624X Dergi Bilgileri (2017) | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 02-2017 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 31-10-2016 |
| Cilt / Sayı / Sayfa | 55 / 3 / 411–418 | DOI | 10.1002/pola.28403 |
| Makale Linki | http://doi.wiley.com/10.1002/pola.28403 | ||
| UAK Araştırma Alanları |
Polimer Bilimi
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| Özet |
| Novel fluorinated coating containing well‐dispersed silicate nanolayers is successfully produced via in‐situ free radical polymerization of 2,2,2‐trifluoroethyl methacrylate in the presence of vinylbenzyl‐functionalized montmorillonite with different loading. The organic modification of sodium montmorillonite is achieved through an ion exchange reaction with triphenylvinylbenzylphosphonium chloride as surfactant prepared before use by reaction with vinylbenyl chloride and phosphine. The following in‐situ polymerization in the presence of organomodified clay leads to fluorinated nanocomposites with of partially exfoliated and intercalated morphologies, as determined via XRD and TEM analysis. The nanoscale dispersion of clay layers is also evidenced by thermal analysis; a moderate decrease of the glass transition temperature about 2–8 °C compared to their virgin PMATRIF and an improvement of their thermal … |
| Anahtar Kelimeler |
| nanocomposites | organoclay | radical polymerization |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Yöksis | 3 |
| Scopus | 33 |
| Google Scholar | 38 |