Synthesis of self-curable polysulfone containing pendant benzoxazine units via CuAAC click chemistry
Yazarlar (3)
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
Cemil Dızman
Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK)
Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK)
Çagatay Altınkök Yalova Üniversitesi
| Makale Türü |
Özgün Makale
(SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
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| Dergi Adı | Designed Monomers and Polymers | ||
| Dergi ISSN | 1568-5551 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 11-2017 |
| Kabul Tarihi | 28-10-2016 | Yayınlanma Tarihi | 21-11-2016 |
| Cilt / Sayı / Sayfa | 20 / 1 / 293–299 | DOI | 10.1080/15685551.2016.1257379 |
| Makale Linki | https://www.tandfonline.com/doi/full/10.1080/15685551.2016.1257379 | ||
| Özet |
| Synthesis, characterization, and properties of new thermally curable polysulfone containing benzoxazine moieties in the side chain were investigated. First, chloromethylation and subsequent azidation processes were performed to form polysulfone containing pendant clickable azide groups. Independently, antagonist 3,4-dihydro-3-(prop-2-ynyl)-2H-benzoxazine was prepared by using paraformaldehyde, phenol and propargylamine. The following copper(I) catalyzed azide-alkyne cycloaddition click reaction was applied to obtain self-curable polysulfone with pendant benzoxazine units. The polymer and intermediates at various stages were characterized by H-NMR, C-NMR and FT-IR spectroscopies. The thermal properties and curing behavior of final polymer were investigated by differential scanning calorimetry and thermal gravimetric analysis. Compared to the neat polysulfone, the obtained polymers exhibited thermally more stable polymers. |
| Anahtar Kelimeler |
| Benzoxazine | click chemistry | cross-linking | polybenzoxazine | polysulfone |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları |