Photoinduced Cu 0 Mediated Atom Transfer Radical Polymerization
Yazarlar (4)
Senem Körk
İstanbul Teknik Üniversitesi, Türkiye
İstanbul Teknik Üniversitesi, Türkiye
Prof. Dr. Mustafa Çiftçi Bursa Teknik Üniversitesi, Türkiye
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
Öğr. Gör. Yusuf Yağcı İstanbul Teknik Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Macromolecular Chemistry and Physics (Q2) | ||
| Dergi ISSN | 1022-1352 Dergi Bilgileri (2016) | ||
| Dergi Tarandığı Indeksler | SSCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 03-2016 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 03-02-2016 |
| Cilt / Sayı / Sayfa | 217 / 6 / 812–817 | DOI | 10.1002/macp.201500456 |
| Makale Linki | http://doi.wiley.com/10.1002/macp.201500456 | ||
| UAK Araştırma Alanları |
Polimer Bilimi
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| Özet |
| Photoinduced Cu(0)‐mediated atom transfer radical polymerization (ATRP) of methyl methacrylate is investigated by using Cu(0)/N,N,N′,N″,N″‐pentamethyldiethylenetriamine as the catalyst, ethyl 2‐bromopropionate as the initiator, and dimethyl sulfoxide as the solvent. The effect of light on the conventional Cu(0)‐mediated ATRP and molecular weight characteristics of the obtained polymers are described. Although the polymerization can be achieved in the absence of light, low initiation efficiency of the process is observed. By introducing UV light and additional Cu(II) deactivator, not only the rate of polymerization is increased, but also well‐controlled polymers with narrow‐molecular‐weight distributions at ambient conditions are obtained. The chain extension study clearly confirms high end‐group fidelity of the polymer that is active in the further polymerization process. |
| Anahtar Kelimeler |
| atom transfer radical polymerization (ATRP) | heterogeneous catalyst | metal-organic catalysts/organometallic catalysts | photopolymerization | supplemental activator and reducing agent ATRP |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Scopus | 12 |
| Google Scholar | 15 |