Macromolecular Design and Application Using Mn2 CO 10 Based Visible Light Photoinitiating Systems
Yazarlar (3)
Mustafa Çiftçi Bursa Teknik Üniversitesi, Türkiye
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
Yusuf Yağcı İstanbul Teknik Üniversitesi, Türkiye
Makale Türü Diğer (Teknik, not, yorum, vaka takdimi, editöre mektup, özet, kitap krıtiği, araştırma notu, bilirkişi raporu ve benzeri) (SCI, SSCI, AHCI, SCI-Exp dergilerinde yayınlanan teknik not, editöre mektup, tartışma, vaka takdimi ve özet türünden makale)
Dergi Adı Polymer International
Dergi ISSN 0959-8103 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SSCI
Makale Dili İngilizce Basım Tarihi 09-2016
Kabul Tarihi 09-03-2016 Yayınlanma Tarihi 19-04-2016
Cilt / Sayı / Sayfa 65 / 9 / 1001–1014 DOI 10.1002/pi.5111
Makale Linki http://doi.wiley.com/10.1002/pi.5111
Özet
The environmentally friendly Mn-2(CO)(10)-based visible light photoinitiating system is a powerful method for the preparation of linear and crosslinked polymeric structures. From a practical point of view, the most important feature of this initiating system is its optical characteristics in the visible range with high quantum yield and good solubility properties. This photoinitiating system is applicable for a variety of monomers that can be polymerized via either radical or cationic mechanisms. Various complex macromolecular structures such as telechelic polymers, block and graft copolymers, polymer networks and surface modifications can be simply prepared by using halogenated precursors. This photoinitiating system is also combined with controlled radical polymerization techniques providing a mild and efficient method for polymer synthesis. (c) 2016 Society of Chemical Industry
Anahtar Kelimeler
metal carbonyls | metal-organic catalysts | photopolymerization | polymer synthesis | radical polymerization