Graft copolymers from commercial chlorinated polypropylene via Cu 0 mediated atom transfer radical polymerization
Yazarlar (2)
Gökhan Açık Piri Reis Üniversitesi, Türkiye
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Polymer International | ||
| Dergi ISSN | 0959-8103 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SSCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 12-2016 |
| Kabul Tarihi | 20-07-2016 | Yayınlanma Tarihi | 02-09-2016 |
| Cilt / Sayı / Sayfa | 65 / 12 / 1458–1463 | DOI | 10.1002/pi.5202 |
| Makale Linki | http://doi.wiley.com/10.1002/pi.5202 | ||
| Özet |
| Commercially available chlorinated polypropylene has been used as a macroinitiator for the Cu(0)-mediated atom transfer radical polymerization of methyl methacrylate and tert-butyl acrylate to obtain well-defined graft copolymers. The relatively narrow molecular weight distribution in the graft copolymers and linear kinetic plots indicated the controlled nature of the copolymerization reactions. Both Fourier transform infrared and H-1 NMR studies confirmed that the graft reactions had taken place successfully. After graft copolymer formation, tert-butyl groups of poly(tert-butyl acrylate) side chains were completely converted into poly(acrylic acid) chains to afford corresponding amphiphilic graft copolymers. (c) 2016 Society of Chemical Industry |
| Anahtar Kelimeler |
| atom transfer radical polymerization (ATRP) | chlorinated polypropylene | heterogeneous catalyst | graft copolymers | polyolefins |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları |