Graft copolymers from commercial chlorinated polypropylene via Cu 0 mediated atom transfer radical polymerization
Yazarlar (2)
Doç. Dr. Gökhan Açık Piri Reis Üniversitesi, Türkiye
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı POLYMER INTERNATIONAL (Q2)
Dergi ISSN 0959-8103 Dergi Bilgileri (2016)
Dergi Tarandığı Indeksler SSCI
Makale Dili İngilizce Basım Tarihi 12-2016
Kabul Tarihi 20-07-2016 Yayınlanma Tarihi 02-09-2016
Cilt / Sayı / Sayfa 65 / 12 / 1458–1463 DOI 10.1002/pi.5202
Makale Linki http://doi.wiley.com/10.1002/pi.5202
UAK Araştırma Alanları
Polimer Bilimi
Özet
Commercially available chlorinated polypropylene has been used as a macroinitiator for the Cu(0)-mediated atom transfer radical polymerization of methyl methacrylate and tert-butyl acrylate to obtain well-defined graft copolymers. The relatively narrow molecular weight distribution in the graft copolymers and linear kinetic plots indicated the controlled nature of the copolymerization reactions. Both Fourier transform infrared and H-1 NMR studies confirmed that the graft reactions had taken place successfully. After graft copolymer formation, tert-butyl groups of poly(tert-butyl acrylate) side chains were completely converted into poly(acrylic acid) chains to afford corresponding amphiphilic graft copolymers. (c) 2016 Society of Chemical Industry
Anahtar Kelimeler
atom transfer radical polymerization (ATRP) | chlorinated polypropylene | heterogeneous catalyst | graft copolymers | polyolefins
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Web of Science 24
Graft copolymers from commercial chlorinated polypropylene via Cu 0 mediated atom transfer radical polymerization

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