POSS based hybrid thermosets via photoinduced copper catalyzed azide alkyne cycloaddition click chemistry
Yazarlar (2)
Arş. Gör. İrem Arslan Yalova Üniversitesi, Türkiye
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
|
||
| Dergi Adı | Designed Monomers and Polymers (Q3) | ||
| Dergi ISSN | 1385-772X Dergi Bilgileri (2016) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2016 |
| Kabul Tarihi | 03-11-2015 | Yayınlanma Tarihi | 22-12-2015 |
| Cilt / Sayı / Sayfa | 19 / 2 / 155–160 | DOI | 10.1080/15685551.2015.1124323 |
| Makale Linki | http://www.tandfonline.com/doi/full/10.1080/15685551.2015.1124323 | ||
| UAK Araştırma Alanları |
Polimer Bilimi
|
||
| Özet |
| An efficient approach for the preparation of inorganic/organic hybrid thermosets via photoinduced copper-catalyzed azide–alkyne cycloaddition click chemistry is established. Highly cross-linked thermoset polymers have been practically obtained by this technique using multifunctional compounds, tri-alkyne (1,1,1-tris[4-(2-propynyloxy) phenyl]-ethane) with octakis-azido-POSS or tri-azide (3,3′-((2-((3-azido-2-hydroxypropoxy)methyl)-2-ethylpropane-1,3-diyl)bis(oxy))bis(1-azidopropan-2-ol)) in the presence of Cu(II)Br2/N,N,N′,N″,N‴-pentamethyldiethylenetriamine/2-dimethoxy-2-phenyl acetophenone. The homogeneously distributed POSS nanoparticles are clearly detected in the TEM micrographs; whereas the TGA analysis shows that the obtained hybrid thermosets are thermally stable up to 360 °C and begin to lose weight at higher temperatures with a char yield of 23–50% at 800 °C. |
| Anahtar Kelimeler |
| Click chemistry | Copper-catalyzed azidealkyne cycloaddition | Hybrid networks | Nanocomposites | Photoinduced reactions | Polyhedral oligomeric silsesquioxane |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Yöksis | 1 |
| Scopus | 29 |
| Google Scholar | 31 |