Visible Light Induced Atom Transfer Radical Polymerization
Yazarlar (4)
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
Mustafa Çiftçi Bursa Teknik Üniversitesi, Türkiye
Yusuf Yağcı İstanbul Teknik Üniversitesi, Türkiye
Umut Parlıtı Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Macromolecular Chemistry and Physics | ||
| Dergi ISSN | 1022-1352 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SSCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 07-2012 |
| Cilt / Sayı / Sayfa | 213 / 13 / 1391–1396 | DOI | 10.1002/macp.201200204 |
| Makale Linki | http://doi.wiley.com/10.1002/macp.201200204 | ||
| Özet |
| Visible light-induced reverse and simultaneous reverse and normal initiation (SR&NI) atom transfer radical polymerizations of vinyl monomers are examined using various dyes and type I photoinitiators. The effect of photoinitiator types on the control of molecular weight and distribution is described. In both dye and type I photoinitiator sensitized SR&NI ATRP systems, the molecular weights increase linearly with conversion. However, the experimental molecular weights are considerably higher than the theoretical values and the polymers show broad-molecular-weight distributions ranging from 1.28 to 1.60 in the dye-sensitized SR&NI ATRP. However, the polymers obtained by SR&NI ATRP using type I photoinitiator system had molecular weight values close to the theoretical ones and very narrow-molecular-weight distributions ranging from 1.111.18. |
| Anahtar Kelimeler |
| atom transfer radical polymerization | controlled radical polymerization | metal-organic catalysts | organometallic catalysts | photopolymerization | simultaneous reverse and normal initiation ATRP | visible light polymerization |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları |