Photoinduced Controlled Radical Polymerization in Methanol
Yazarlar (5)
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
Mustafa Uygun Istanbul Technical University
Yusuf Yağcı İstanbul Teknik Üniversitesi, Türkiye
Mehmet Cengiz Türkiye
Artay Yağcı Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Macromolecular Chemistry and Physics | ||
| Dergi ISSN | 1022-1352 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SSCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 11-2010 |
| Cilt / Sayı / Sayfa | 211 / 21 / 2271–2275 | DOI | 10.1002/macp.201000445 |
| Makale Linki | http://doi.wiley.com/10.1002/macp.201000445 | ||
| Özet |
| Photoinduced CRP of methyl methacrylate initiated by in situ generation of copper ( I) complex from higher oxidation state species in methanol was investigated. The polymerizations proceeded in a well-controlled manner under UV light at room temperature as evidenced by kinetic and chain extension studies. The evolution of molecular weight with conversion showed good correlation between experimental and theoretical molecular weights, which confirmed good control over polymerization and ensured a narrow MWD. The effect of the methanol on the polymerization was also investigated, and a better agreement between experimental and theoretical molecular weights with a quite narrow MWD was obtained by using methanol as solvent. |
| Anahtar Kelimeler |
| atom-transfer radical polymerization (ATRP) | living polymerization | metal-organic catalysts/organometallic catalysts | photochemistry | photopolymerization |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları |