Influence of Type of Initiation on Thiol Ene Click Chemistry
Yazarlar (3)
Mustafa Uygun
Istanbul Technical University, Türkiye
Istanbul Technical University, Türkiye
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
Öğr. Gör. Yusuf Yağcı İstanbul Teknik Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Macromolecular Chemistry and Physics (Q1) | ||
| Dergi ISSN | 1022-1352 Dergi Bilgileri (2010) | ||
| Dergi Tarandığı Indeksler | SSCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2010 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 23-12-2009 |
| Cilt / Sayı / Sayfa | 211 / 1 / 103–110 | DOI | 10.1002/macp.200900442 |
| Makale Linki | http://doi.wiley.com/10.1002/macp.200900442 | ||
| UAK Araştırma Alanları |
Polimer Bilimi
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| Özet |
| Thermally and photochemically initiated thiol–ene click reactions using thiol‐ and allyl‐ end functionalized linear polystyrenes with various enes (allyl bromide, methyl acrylate, and methyl methacrylate) and thiol (3‐mercaptopropionic acid) have been investigated. Allyl‐ and thiol‐end‐capped polystyrenes with controlled molecular weight and low polydispersity were prepared by atom transfer radical polymerization (ATRP) of styrene using functional initiator and end group modification approaches, respectively. Thiol–ene reactions can be initiated by both cleavage type photoinitiators such as (2,4,6‐trimethylbenzoyl)diphenylphosphine oxide (TMDPO) and 2,2‐dimethoxy‐2‐phenyl acetophenone (DMPA) and H‐abstraction type photoinitiators such as benzophenone (BP), thioxanthone (TX), camphorquinone (CQ), and classical thermal initiator, 2,2′‐azobis(isobutyronitrile) (AIBN) at 80 °C. The kinetics of the … |
| Anahtar Kelimeler |
| Atom transfer radical polymerization (ATRP) | Click chemistry | Functionalization of polymers | Photoinitiation | Thiol-ene reactions |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Yöksis | 67 |
| Web of Science | 236 |
| Scopus | 248 |
| Google Scholar | 351 |