In Situ Synthesis of A 3 Type Star Polymer Clay Nanocomposites by AtomTransfer Radical Polymerization
Yazarlar (4)
Muhammed Aydın Istanbul Technical University
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
Tamer Uyar
İhsan Doğramacı Bilkent Üniversitesi, Türkiye
İhsan Doğramacı Bilkent Üniversitesi, Türkiye
Yusuf Yağcı İstanbul Teknik Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | ||
| Dergi ISSN | 0887-624X | ||
| Dergi Tarandığı Indeksler | SSCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2013 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 11-10-2013 |
| Cilt / Sayı / Sayfa | 51 / 24 / 5257–5262 | DOI | 10.1002/pola.26957 |
| Makale Linki | http://doi.wiley.com/10.1002/pola.26957 | ||
| Özet |
| A series of A(3)-type star poly(methylmethacrylate)/clay nanocomposites is prepared by in situ atom transfer radical polymerization (ATRP) initiated from organomodified montmorillonite containing quaternary trifunctional ATRP initiator. The first order kinetic plot shows a linear behavior, indicating the controlled character of the polymerization. The resulting nanocomposites are characterized by spectroscopic (XRD), thermal (DSC and TGA), and microscopic (TEM) analyses. The exfoliated nanocomposite has been obtained when polymerization was conducted with 1% of organic clay loading. Thermal analyses show that all nanocomposites have higher glass transition values and thermal stabilities compared to neat polymer. (c) 2013 Wiley Periodicals, Inc. |
| Anahtar Kelimeler |
| atom transfer radical polymerization | in situ polymerization | nanoclay | nanocomposites | star polymers |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları |