Photoinitiated ATRP in Inverse Microemulsion
Yazarlar (9)
Prof. Dr. Mustafa Çiftçi Bursa Teknik Üniversitesi, Türkiye
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
Wenwen Li Carnegie Mellon University, Amerika Birleşik Devletleri
Krzysztof Matyjaszewski Carnegie Mellon University, Amerika Birleşik Devletleri
Öğr. Gör. Yusuf Yağcı İstanbul Teknik Üniversitesi, Türkiye
Damla Aykora
Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı MACROMOLECULES (Q1)
Dergi ISSN 0024-9297 Dergi Bilgileri (2013)
Dergi Tarandığı Indeksler SSCI
Makale Dili İngilizce Basım Tarihi 12-2013
Kabul Tarihi Yayınlanma Tarihi 11-12-2013
Cilt / Sayı / Sayfa 46 / 24 / 9537–9543 DOI 10.1021/ma402058a
Makale Linki https://pubs.acs.org/doi/10.1021/ma402058a
UAK Araştırma Alanları
Polimer Bilimi
Özet
The recently developed photoinitiated atom transfer radical polymerization has been implemented in the inverse microemulsion polymerization of oligo(ethylene glycol) monomethyl ether methacrylate. Two different mechanisms including a simultaneous reverse and normal initiated ATRP and a combination of activators generated by electron transfer and initiators for continuous activator regeneration ATRP are investigated under UV light. The effects of various reaction parameters on the resulting particles have been systematically investigated, and it has been demonstrated that the particle size can be tuned based on UV light, initial stoichiometry, and aqueous phase fraction. The formed particles contained well-defined water-soluble polymers with relatively narrow molecular weight distribution (M-w/M-n < 1.4).
Anahtar Kelimeler
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Web of Science 118
Photoinitiated ATRP in Inverse Microemulsion

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