Photoinitiated ATRP in Inverse Microemulsion
Yazarlar (9)
Mustafa Çiftçi Bursa Teknik Üniversitesi, Türkiye
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
Wenwen Li
Carnegie Mellon University
Carnegie Mellon University
Krzysztof Matyjaszewski
Carnegie Mellon University
Carnegie Mellon University
Yusuf Yağcı İstanbul Teknik Üniversitesi, Türkiye
Cemre Aydeğer Türkiye
Hüseyin Avni Eroğlu Türkiye
Şeyma Savaş
Türkiye
Türkiye
Damla Aykora
Türkiye
Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | MACROMOLECULES | ||
| Dergi ISSN | 0024-9297 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SSCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2013 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 11-12-2013 |
| Cilt / Sayı / Sayfa | 46 / 24 / 9537–9543 | DOI | 10.1021/ma402058a |
| Makale Linki | https://pubs.acs.org/doi/10.1021/ma402058a | ||
| Özet |
| The recently developed photoinitiated atom transfer radical polymerization has been implemented in the inverse microemulsion polymerization of oligo(ethylene glycol) monomethyl ether methacrylate. Two different mechanisms including a simultaneous reverse and normal initiated ATRP and a combination of activators generated by electron transfer and initiators for continuous activator regeneration ATRP are investigated under UV light. The effects of various reaction parameters on the resulting particles have been systematically investigated, and it has been demonstrated that the particle size can be tuned based on UV light, initial stoichiometry, and aqueous phase fraction. The formed particles contained well-defined water-soluble polymers with relatively narrow molecular weight distribution (M-w/M-n < 1.4). |
| Anahtar Kelimeler |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları |