Reduction of Cu II by photochemically generated phosphonyl radicals to generate Cu I as catalyst for atom transfer radical polymerization and azide alkyne cycloaddition click reactions
Yazarlar (3)
Öğr. Gör. Yusuf Yağcı İstanbul Teknik Üniversitesi, Türkiye
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
Jockusch Steffen
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | POLYMER (Q1) | ||
| Dergi ISSN | 0032-3861 Dergi Bilgileri (2014) | ||
| Dergi Tarandığı Indeksler | SSCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 08-2014 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-08-2014 |
| Cilt / Sayı / Sayfa | 55 / 16 / 3468–3474 | DOI | 10.1016/j.polymer.2014.06.068 |
| Makale Linki | http://linkinghub.elsevier.com/retrieve/pii/S003238611400562X | ||
| UAK Araştırma Alanları |
Polimer Bilimi
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| Özet |
| The photoinduced electron transfer reactions of acylphosphine oxide type photoinitiators with Cu(II)Cl-2/N,N,N',N '',N ''-pentamethyldiethylenetriamine complex for both atom transfer radical polymerization and copper catalyzed azide-alkyne cycloaddition processes is investigated by laser flash photolysis. The photolytically generated phosphonyl radicals are effective in reducing Cu(II) salts to Cu(I) with rate constants of similar to 2 x 10(9) M-1 s(-1). (C) 2014 Elsevier Ltd. All rights reserved. |
| Anahtar Kelimeler |
| Acylphosphine oxides | Photoinduced electron transfer reactions | Copper catalyst |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 70 |