Reduction of Cu II by photochemically generated phosphonyl radicals to generate Cu I as catalyst for atom transfer radical polymerization and azide alkyne cycloaddition click reactions
Yazarlar (3)
Öğr. Gör. Yusuf Yagci İstanbul Teknik Üniversitesi, Türkiye
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
Steffen Jockusch
Columbia University, Amerika Birleşik Devletleri
Columbia University, Amerika Birleşik Devletleri
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Polymer (Q1) | ||
| Dergi ISSN | 0032-3861 Dergi Bilgileri (2014) | ||
| Dergi Tarandığı Indeksler | SSCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 08-2014 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-08-2014 |
| Cilt / Sayı / Sayfa | 55 / 16 / 3468–3474 | DOI | 10.1016/j.polymer.2014.06.068 |
| Makale Linki | http://linkinghub.elsevier.com/retrieve/pii/S003238611400562X | ||
| UAK Araştırma Alanları |
Polimer Bilimi
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| Özet |
| The photoinduced electron transfer reactions of acylphosphine oxide type photoinitiators with Cu(II)Cl2/N,N,N′,N′′,N′′-pentamethyldiethylenetriamine complex for both atom transfer radical polymerization and copper catalyzed azide-alkyne cycloaddition processes is investigated by laser flash photolysis. The photolytically generated phosphonyl radicals are effective in reducing Cu(II) salts to Cu(I) with rate constants of ∼2 × 109 M−1 s−1. |
| Anahtar Kelimeler |
| Acylphosphine oxides | Copper catalyst | Photoinduced electron transfer reactions |
Science Direct
Reduction of Cu II by photochemically generated phosphonyl radicals to generate Cu I as catalyst for atom transfer radical polymerization and azide alkyne cycloaddition click reactions
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| Yöksis | 10 |
| Web of Science | 70 |
| Scopus | 70 |
| Google Scholar | 82 |