Photoinitiated atom transfer radical polymerization Current status and future perspectives
Yazarlar (3)
Dadashi-Silab Sajjad
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
Yusuf Yağcı İstanbul Teknik Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Polymer Science Part A: Polymer Chemistry | ||
| Dergi ISSN | 0887-624X | ||
| Dergi Tarandığı Indeksler | SSCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 10-2014 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 06-08-2014 |
| Cilt / Sayı / Sayfa | 52 / 20 / 2878–2888 | DOI | 10.1002/pola.27327 |
| Makale Linki | http://doi.wiley.com/10.1002/pola.27327 | ||
| Özet |
| In macromolecular and material science, atom transfer radical polymerization (ATRP) has intensely influenced the research strategies facilitating fabrication of a wide range of polymers with well-defined structures and functions and their conjugation with biomolecules. Recently, the required copper (I) catalyst for ATRP process is generated by photoinduced redox reactions involving the in situ reduction of Cu(II) to Cu(I). Photochemically initiated reactions provide several distinct advantages, including temporal and spatial controls, rapid and energy efficient activation. The process is based on photoredox reactions of copper catalysts under various radiation sources with or without various photoinitiators. This Highlight focuses on the historical development, mechanistic aspects, limitations, and opportunities of photoinitiated ATRP along with selected examples. (C) 2014 Wiley Periodicals, Inc. |
| Anahtar Kelimeler |
| atom transfer radical polymerization (ATRP) | metal-organic catalysts/organometallic catalysts | photochemistry | photopolymerization | radical polymerization |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları |