Poly epsilon caprolactone clay nanocomposites via host guest chemistry
Yazarlar (7)
Mustafa Arslan Kırklareli Üniversitesi, Türkiye
Tamer Uyar
İhsan Doğramacı Bilkent Üniversitesi, Türkiye
İhsan Doğramacı Bilkent Üniversitesi, Türkiye
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
Yusuf Yağcı İstanbul Teknik Üniversitesi, Türkiye
Tuba Mızrak
Tuba Mızrak
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | European Polymer Journal | ||
| Dergi ISSN | 0014-3057 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SSCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 10-2015 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-10-2015 |
| Cilt / Sayı / Sayfa | 71 / 0 / 259–267 | DOI | 10.1016/j.eurpolymj.2015.08.006 |
| Makale Linki | http://linkinghub.elsevier.com/retrieve/pii/S001430571500422X | ||
| Özet |
| Cyclodextrin-modified montmorillonite (MMT-CD) has been prepared from commercial montmorillonite clay (Closite 30B) containing two hydroxyl groups by reacting succinic anhydride through esterification. Poly(epsilon caprolactone) (PCL)/clay nanocomposites are prepared by host-guest chemistry between MMT-CD as host and PCL, hydrophobic polymer as guest. The structures of the intermediates and final nanocomposite are investigated in detail by FT-IR XRD, TEM, DSC and TGA measurements. The intercalated/exfoliated morphologies are determined by combined XRD and TEM analyses. Thermal stabilities of all nanocomposites are improved by the addition of MMT-CD compared to the neat polymer. The DSC data confirm that the crystallinity of PCL is slightly increased by increasing clay loading. (C) 2015 Elsevier Ltd. All rights reserved. |
| Anahtar Kelimeler |
| Cyclodextrin | Host-guest chemistry | Nanocomposites | Organoclay | Ring-opening polymerization | Self-assembly |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları |