New Photoinitiating Systems for Cationic Polymerization Acting at Near UV and Visible Range
Yazarlar (8)
Stanislaw Penczek
Andrzej Duda
Mustafa Uygun
M. Atilla Tasdelen
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Macromolecular Symposia | ||
| Dergi ISSN | 1022-1360 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 10-2011 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-10-2011 |
| Cilt / Sayı / Sayfa | 308 / 1 / 25–34 | DOI | 10.1002/masy.201151005 |
| Makale Linki | http://doi.wiley.com/10.1002/masy.201151005 | ||
| Özet |
| New photoiniting systems for cationic polymerization acting at near UV and visible range are described. The applicability of acylgermanes as a new class of free radical promoters for photoinitiated cationic polymerization is demonstrated. Moreover, the use of substituted vinyl halides as source for readily oxidizable free radicals is presented. The polymerization of vinyl ethers can be initiated by the irradiation of substituted vinyl halides in the presence of Lewis acids such as zinc halide. Furthermore, possibilities for conducting cationic polymerization at visible range by using highly conjugated thiophene derivatives are demonstrated. Mechanistic aspects of all initiating systems are discussed. |
| Anahtar Kelimeler |
| acyl german | cationic polymerization | dithienothiophene | photopolymerization | vinyl halides |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları |