Thermally Curable Polyoxanorbornene by Ring Opening Metathesis Polymerization
Yazarlar (2)
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
Prof. Dr. Hakan Durmaz İstanbul Teknik Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Macromolecular Chemistry and Physics (Q1)
Dergi ISSN 1022-1352 Dergi Bilgileri (2011)
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce Basım Tarihi 10-2011
Kabul Tarihi – Yayınlanma Tarihi 19-08-2011
Cilt / Sayı / Sayfa 212 / 19 / 2121–2126 DOI 10.1002/macp.201100258
Makale Linki http://doi.wiley.com/10.1002/macp.201100258
UAK Araştırma Alanları
Polimer Bilimi
Özet
A novel norbornene monomer bearing a thermally curable benzoxazine group is synthesized and polymerized by ROMP using the Grubbs first‐generation ruthenium catalyst. The M_\rmw of the side‐chain benzoxazine functionalized polyoxanorbornene can be up to 87 000 Da with unimodal molecular‐weight distribution and narrow polydispersity between 1.18 and 1.65. Thermally activated ring‐opening polymerization of benzoxazine moieties leads to the formation of highly cross‐linked structures. The effects of molecular weight on the thermal ROP of polybenzoxazine precursors are examined.
Anahtar Kelimeler
benzoxazine resins | high-performance thermosets | polybenzoxazines | polyoxanorbornenes | ring-opening metathesis polymerization
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Web of Science 10
Scopus 10
Google Scholar 11
Thermally Curable Polyoxanorbornene by Ring Opening Metathesis Polymerization