Thermally Curable Polyoxanorbornene by Ring Opening Metathesis Polymerization
Yazarlar (2)
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Macromolecular Chemistry and Physics | ||
| Dergi ISSN | 1022-1352 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 10-2011 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 19-08-2011 |
| Cilt / Sayı / Sayfa | 212 / 19 / 2121–2126 | DOI | 10.1002/macp.201100258 |
| Makale Linki | http://doi.wiley.com/10.1002/macp.201100258 | ||
| Özet |
| A novel norbornene monomer bearing a thermally curable benzoxazine group is synthesized and polymerized by ROMP using the Grubbs first-generation ruthenium catalyst. The (M) over bar (w) of the side-chain benzoxazine functionalized polyoxanorbornene can be up to 87 000 Da with unimodal molecular-weight distribution and narrow polydispersity between 1.18 and 1.65. Thermally activated ring-opening polymerization of benzoxazine moieties leads to the formation of highly cross-linked structures. The effects of molecular weight on the thermal ROP of polybenzoxazine precursors are examined. |
| Anahtar Kelimeler |
| benzoxazine resins | high-performance thermosets | polybenzoxazines | polyoxanorbornenes | ring-opening metathesis polymerization |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları |