Poly p phenylene methylene based block copolymers by mechanistic transformation
Yazarlar (7)
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
Selim Beyazit
İstanbul Teknik Üniversitesi, Türkiye
İstanbul Teknik Üniversitesi, Türkiye
Doç. Dr. Deniz Gunes İstanbul Teknik Üniversitesi, Türkiye
Niyazi Bicak
İstanbul Teknik Üniversitesi, Türkiye
İstanbul Teknik Üniversitesi, Türkiye
Pinar Tatar
Koç University, Türkiye
Koç University, Türkiye
A. Levent Demirel
Koç University, Türkiye
Koç University, Türkiye
Öğr. Gör. Yusuf Yagci İstanbul Teknik Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Polymer Science Part A Polymer Chemistry (Q1) | ||
| Dergi ISSN | 0887-624X Dergi Bilgileri (2011) | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 09-2011 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 07-07-2011 |
| Cilt / Sayı / Sayfa | 49 / 18 / 4021–4026 | DOI | 10.1002/pola.24844 |
| Makale Linki | http://doi.wiley.com/10.1002/pola.24844 | ||
| UAK Araştırma Alanları |
Polimer Bilimi
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| Özet |
| The synthesis of poly(p‐phenylene methylene) (PPM)‐based block copolymers such as poly(p‐phenylene methylene)‐b‐poly(ε‐caprolactone) and poly(p‐phenylene methylene)‐b‐polytetrahydrofuran by mechanistic transformation was described. First, precursor PPM was synthesized by acid‐catalyzed polymerization of tribenzylborate at 16 °C. Then, this polymer was used as macroinitiators in either ring‐opening polymerization of ε‐caprolactone or cationic ring‐opening polymerization of tetrahydrofuran to yield respective block copolymers. The structures of the prepolymer and block copolymers were characterized by GPC and 1H NMR investigations. The composition of block copolymers as determined by 1H NMR and TGA analysis was found to be in very good agreement. The thermal behavior and surface morphology of the copolymers were also investigated, respectively, by differential scanning calorimetry … |
| Anahtar Kelimeler |
| block copolymers | cationic polymerization | cationic ring-opening polymerization | poly(ε-caprolactone) | poly(p-phenylene methylene) | polybenzyl | polytetrahydrofuran | ring-opening polymerization |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 7 |
| Scopus | 7 |
| Google Scholar | 8 |