Photochemical Methods for the Preparation of Complex Linear and Cross linked Macromolecular Structures
Yazarlar (2)
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Australian Journal of Chemistry
Dergi ISSN 0004-9425 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce Basım Tarihi 01-2011
Kabul Tarihi Yayınlanma Tarihi 19-08-2011
Cilt / Sayı / Sayfa 64 / 8 / 982–991 DOI 10.1071/CH11113
Makale Linki http://www.publish.csiro.au/?paper=CH11113
Özet
In this contribution, the current state of the art is summarized and an overview of photoinitiating systems for both radical and cationic polymerizations and their potential application in the preparation of complex linear and cross-linked macromolecular structures are described. Recent relevant studies have been devoted to developing novel free radical and cationic photoinitiators having spectroscopic sensitivity in the near-UV or visible range. Photoinitiated controlled radical polymerization methods leading to tailor-made polymers with predetermined structure and architecture are briefly presented. Several synthetic methodologies for the preparation of epoxy and (meth) acrylate based formulations containing clay or metal nanoparticles are also summarized. The nanoparticles are homogenously distributed in the network without macroscopic agglomeration. Applicability to both free radical and cationic systems is demonstrated.
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