Poly methyl methacrylate clay nanocomposites by photoinitiated free radical polymerization using intercalated monomer
Yazarlar (4)
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Polymer | ||
| Dergi ISSN | 0032-3861 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 07-2009 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-07-2009 |
| Cilt / Sayı / Sayfa | 50 / 16 / 3905–3910 | DOI | 10.1016/j.polymer.2009.06.020 |
| Makale Linki | http://linkinghub.elsevier.com/retrieve/pii/S0032386109004984 | ||
| Özet |
| A series of poly(methyl methacrylate)/montmorillonite (PMMA/MMT) nanocomposite were prepared by Successfully dispersing the inorganic nanolayers of MMT clay in an organic PMMA matrix via in situ photoinitiated free radical polymerization. Methyl methacrylate monomer was first intercalated into the interlayer regions of organophilic clay hosts by "click" chemistry followed by a typical photoinitiated free radical polymerization. The intercalated monomer was characterized by FT-IR spectroscopy, elemental analysis and thermogravimetric analysis methods. The intercalation ability of the modified monomer and exfoliated nanocomposite structure were confirmed by X-ray diffraction spectroscopy (XRD), transmission electron microscopy (TEM) and atomic force microscopy (AFM). Thermal stability of PMMA/MMT nanocomposites was also studied by both differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). (c) 2009 Elsevier Ltd. All rights reserved. |
| Anahtar Kelimeler |
| Nanocomposites | Click chemistry | Poly(methyl methacrylate) |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları |