The use of poly ethylene oxide as hydrogen donor in type II photoinitiated free radical polymerization
Yazarlar (3)
Prof. Dr. Mehmet Atilla TAŞDELEN İstanbul Teknik Üniversitesi, Türkiye
Norbert Moszner
Ivoclar Vivadent Ag, Lihtenştayn
Ivoclar Vivadent Ag, Lihtenştayn
Öğr. Gör. Yusuf Yagci İstanbul Teknik Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Polymer Bulletin (Q3) | ||
| Dergi ISSN | 0170-0839 Dergi Bilgileri (2009) | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 08-2009 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 16-04-2009 |
| Cilt / Sayı / Sayfa | 63 / 2 / 173–183 | DOI | 10.1007/s00289-009-0079-2 |
| Makale Linki | http://link.springer.com/10.1007/s00289-009-0079-2 | ||
| UAK Araştırma Alanları |
Polimer Bilimi
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| Özet |
| The aim of this study was to demonstrate hydrogen donating capability of poly(ethylene oxide) (PEO) in type II photoinitiated free radical polymerization for dental applications. Photopolymerization kinetics of the dental resin mixtures were monitored by Photo-DSC. H-NMR spectroscopic and GPC studies were also performed in order to gain insight to the hydrogen abstraction mechanism. The effect of molecular weight of PEO on the photoinitiation efficiency was investigated. Photolysis of solutions containing benzophenone and PEO in the presence of a radical scavenger namely, 2,2,6,6-tetramethylpiperidine-N-oxyl free radical (TEMPO) revealed that photoexcited benzophenone readily abstracts hydrogen from methylene groups present in PEO backbone. It was demonstrated that such photoinitiating system can be converted to a versatile grafting process. PEO possessing photochemically attached TEMPO units … |
| Anahtar Kelimeler |
| Dental resin | Hydrogen donor | Photopolymerization | Type II photoinitiating system |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 52 |
| Scopus | 58 |
| Google Scholar | 67 |