Synthesis of Poly isobutyl vinyl ether I graft I Poly ethylene oxide Co polymer with Pendant Methacrylate Functionality and Its Photo curing Behavior
Yazarlar (5)
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Designed Monomers & Polymers | ||
| Dergi ISSN | 1385-772X Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 05-2009 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-01-2009 |
| Cilt / Sayı / Sayfa | 12 / 3 / 265–272 | DOI | 10.1163/156855509X436085 |
| Makale Linki | http://booksandjournals.brillonline.com/content/journals/10.1163/156855509x436085 | ||
| Özet |
| Poly(isobutyl vinyl ether)-graft-poly(ethylene oxide) graft co-polymer with pendant methacrylate groups (PIBVE-g-PEO) was obtained by photoinitiated living cationic co-polymerization of isobutyl vinyl ether (IBVE) with alpha-vinyloxy-omega-methacryloyl-poly(ethylene oxide) (VE-PEO-MA) macromonomer. For this purpose, anionically prepared VE-PEO-MA hybrid macromonomer and IBVE were irradiated in the presence of diphenyl iodonium iodide and zinc iodide as photoacid generator and activator, respectively. Successful graft co-polymerization and conservation of pendant double bonds were confirmed by GPC, and H-1-NMR and FT-IR spectral analysis. The free radical photo-cross-linking behavior of the graft co-polymer was demonstrated. (C) Koninklijke Brill NV, Leiden, 2009 |
| Anahtar Kelimeler |
| Photo-polymerization | living cationic polymerization | photo-curing | graft co-polymers | macromonomer |
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