Synthesis of Poly isobutyl vinyl ether I graft I Poly ethylene oxide Co polymer with Pendant Methacrylate Functionality and Its Photo curing Behavior
Yazarlar (5)
Elif Sezin Devrim Istanbul Technical University, Türkiye
Muhammet U. Kahveci
Istanbul Technical University, Türkiye
M. Atilla Tasdelen Istanbul Technical University, Türkiye
Koichi Ito
Toyohashi University of Technology, Japonya
Öğr. Gör. Yusuf Yagci Istanbul Technical University, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı DESIGNED MONOMERS AND POLYMERS (Q3)
Dergi ISSN 1385-772X Dergi Bilgileri (2009)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 01-2009
Kabul Tarihi Yayınlanma Tarihi 01-01-2009
Cilt / Sayı / Sayfa 12 / 3 / 265–272 DOI 10.1163/156855509X436085
Makale Linki http://booksandjournals.brillonline.com/content/journals/10.1163/156855509x436085
UAK Araştırma Alanları
Polimer Bilimi
Özet
Poly(isobutyl vinyl ether)-graft-poly(ethylene oxide) graft co-polymer with pendant methacrylate groups (PIBVE-g-PEO) was obtained by photoinitiated living cationic co-polymerization of isobutyl vinyl ether (IBVE) with alpha-vinyloxy-omega-methacryloyl-poly(ethylene oxide) (VE-PEO-MA) macromonomer. For this purpose, anionically prepared VE-PEO-MA hybrid macromonomer and IBVE were irradiated in the presence of diphenyl iodonium iodide and zinc iodide as photoacid generator and activator, respectively. Successful graft co-polymerization and conservation of pendant double bonds were confirmed by GPC, and H-1-NMR and FT-IR spectral analysis. The free radical photo-cross-linking behavior of the graft co-polymer was demonstrated. (C) Koninklijke Brill NV, Leiden, 2009
Anahtar Kelimeler
Photo-polymerization | living cationic polymerization | photo-curing | graft co-polymers | macromonomer