Poly styrene b tetrahydrofuran clay nanocomposites by mechanistic transformation
Yazarlar (5)
Zuleyha Yenice
Ege Üniversitesi, Türkiye
Ege Üniversitesi, Türkiye
Prof. Dr. Mehmet Atilla TAŞDELEN İstanbul Teknik Üniversitesi, Türkiye
Prof. Dr. Ayhan Oral Çanakkale Onsekiz Mart Üniversitesi, Türkiye
Prof. Dr. Cetin Guler Ege Üniversitesi, Türkiye
Öğr. Gör. Yusuf Yagci İstanbul Teknik Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Polymer Science Part A Polymer Chemistry (Q1) | ||
| Dergi ISSN | 0887-624X Dergi Bilgileri (2009) | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 04-2009 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 11-03-2009 |
| Cilt / Sayı / Sayfa | 47 / 8 / 2190–2197 | DOI | 10.1002/pola.23332 |
| Makale Linki | http://doi.wiley.com/10.1002/pola.23332 | ||
| UAK Araştırma Alanları |
Polimer Bilimi
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| Özet |
| Synthesis of poly(styrene‐block‐tetrahydrofuran) (PSt‐b‐PTHF) block copolymer on the surfaces of intercalated and exfoliated silicate (clay) layers by mechanistic transformation was described. First, the polystyrene/montmorillonite (PSt/MMT) nanocomposite was synthesized by in situ atom transfer radical polymerization (ATRP) from initiator moieties immobilized within the silicate galleries of the clay particles. Transmission electron microscopy (TEM) analysis showed the existence of both intercalated and exfoliated structures in the nanocomposite. Then, the PSt‐b‐PTHF/MMT nanocomposite was prepared by mechanistic transformation from ATRP to cationic ring opening polymerization (CROP). The TGA thermogram of the PSt‐b‐PTHF/MMT nanocomposite has two decomposition stages corresponding to PTHF and PSt segments. All nanocomposites exhibit enhanced thermal stabilities compared with the virgin … |
| Anahtar Kelimeler |
| Atom transfer radical polymerization (ATRP) | Block copolymers | Cationic polymerization | Cationic ring opening polymerization | Clay | Mechanistic transformation | Nanocomposites |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 52 |
| Scopus | 55 |
| Google Scholar | 75 |