Polytetrahydrofuran Clay Nanocomposites by In Situ Polymerization and Click Chemistry Processes
Yazarlar (6)
Prof. Dr. Mehmet Atilla TAŞDELEN İstanbul Teknik Üniversitesi, Türkiye
Wim Van Camp
Universiteit Gent, Belçika
Universiteit Gent, Belçika
Eric Goethals
Universiteit Gent, Belçika
Universiteit Gent, Belçika
Philippe Dubois Université De Mons, Belçika
Filip Du Prez
Universiteit Gent, Belçika
Universiteit Gent, Belçika
Öğr. Gör. Yusuf Yagci İstanbul Teknik Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Macromolecules (Q1) | ||
| Dergi ISSN | 0024-9297 Dergi Bilgileri (2008) | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 08-2008 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 23-07-2008 |
| Cilt / Sayı / Sayfa | 41 / 16 / 6035–6040 | DOI | 10.1021/ma801149x |
| Makale Linki | http://pubs.acs.org/doi/abs/10.1021/ma801149x | ||
| UAK Araştırma Alanları |
Polimer Bilimi
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| Özet |
| Polytetrahydrofuran (PTHF)/clay nanocomposites were prepared by two routes: in situ cationic ring opening polymerization (CROP) and a method involving “click” chemistry. In the first method, PTHF chains were grown from the surface of the organo-modified montmorillonite clay by CROP of tetrahydrofuran (THF) through the hydroxyl functions of the clay by using trifluoromethanesulfonic anhydride, in the presence of 2,6-di-tert-butylpyridine as proton trap and dichloromethane as solvent. The polymerizations were affected by the clay content ratios. The living characteristics of the polymerization were demonstrated by the semilogarithmic first order kinetic plot. In the second method, CROP of THF has been performed independently to produce alkyne-functionalized PTHF and the obtained polymers were subsequently anchored to azide-modified clay layers by a “click” reaction. The exfoliated polymer/clay … |
| Anahtar Kelimeler |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 110 |
| Scopus | 113 |
| Google Scholar | 136 |