Poly propylene imine dendrimers as hydrogen donor in Type II photoinitiated free radical polymerization
Yazarlar (3)
Prof. Dr. Mehmet Atilla TAŞDELEN İstanbul Teknik Üniversitesi, Türkiye
A. Levent Demirel
Koç University, Türkiye
Koç University, Türkiye
Öğr. Gör. Yusuf Yagci İstanbul Teknik Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | European Polymer Journal (Q1) | ||
| Dergi ISSN | 0014-3057 Dergi Bilgileri (2007) | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 10-2007 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-10-2007 |
| Cilt / Sayı / Sayfa | 43 / 10 / 4423–4430 | DOI | 10.1016/j.eurpolymj.2007.05.042 |
| Makale Linki | http://linkinghub.elsevier.com/retrieve/pii/S0014305707004247 | ||
| UAK Araştırma Alanları |
Polimer Bilimi
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| Özet |
| Three generations of poly(propylene imine) dendrimers, namely (PPI-16, PPI-32 and PPI-64; 16, 32 and 64 for generations 3, 4 and 5, respectively) were used as hydrogen donors in photoinitiated free radical polymerization of methyl methacrylate by using one of the following photosensitizers; benzophenone and thioxanthone. The effect of generation number of the dendrimer on photoinitiation efficiency and molecular weight of the resulting polymers was investigated. Glass transition temperatures and particle size measurements of the resulting polymers indicated the presence of nearly stretched polymer chains around the dendrimers. The location of hydrogen donating sites was evaluated by photolysis studies in the absence of monomer by using a stable radical namely, 2,2,6,6-tetramethylpiperidine-N-oxyl free radical (TEMPO) and showed that hydrogen abstraction occurs from the inner tertiary amino groups … |
| Anahtar Kelimeler |
| Dendrimer-star polymers | Free radical polymerization | Methyl methacrylate | Photopolymerization | Poly(propylene imine) dendrimers |
Science Direct
Poly propylene imine dendrimers as hydrogen donor in Type II photoinitiated free radical polymerization
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 46 |
| Scopus | 51 |
| Google Scholar | 58 |