Synthesis and Characterization of Block Graft Copolymers poly epichlorohydrin b styrene g poly methyl methacrylate by Combination of Activated Monomer Polymerization NMP and ATRP
Yazarlar (5)
Prof. Dr. Mehmet Atilla TAŞDELEN İstanbul Teknik Üniversitesi, Türkiye
Öğr. Gör. Yusuf Yagci İstanbul Teknik Üniversitesi, Türkiye
A. Levent Demirel
Koç University, Türkiye
Koç University, Türkiye
Tadeusz Biedron
Institute - Center For Molecular And Macromolecular Studies of The Polish Academy of Sciences, Polonya
Institute - Center For Molecular And Macromolecular Studies of The Polish Academy of Sciences, Polonya
Przerayslaw Kubisa
Institute - Center For Molecular And Macromolecular Studies of The Polish Academy of Sciences, Polonya
Institute - Center For Molecular And Macromolecular Studies of The Polish Academy of Sciences, Polonya
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Polymer Bulletin (Q2) | ||
| Dergi ISSN | 0170-0839 Dergi Bilgileri (2007) | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 04-2007 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 02-12-2006 |
| Cilt / Sayı / Sayfa | 58 / 4 / 653–663 | DOI | 10.1007/s00289-006-0708-y |
| Makale Linki | http://link.springer.com/10.1007/s00289-006-0708-y | ||
| UAK Araştırma Alanları |
Polimer Bilimi
|
||
| Özet |
| Synthesis of block-graft copolymers, namely poly(epichlorohydrin-b-styrene)-g-poly(methyl methacrylate) (PECH-b-St)-g-PMMA) by combination of Activated Monomer (AM), Nitroxide Mediated Polymerization (NMP) and Atom Transfer Radical Polymerization (ATRP) methods was described. For this purpose, first epichlorohydrin (ECH) was polymerized by using BF3THF complex in the presence of 4-hydroxy-2,2,6,6-tetramethyl-1-piperidinyl-1-oxy (HTEMPO) via AM mechanism. The resulting stable radical terminated polymer was subsequently used as a counter radical in the NMP of styrene (St) initiated by benzoyl peroxide to yield block copolymers of ECH and St. Finally, the ATRP of methyl methacrylate (MMA) by using chloromethyl groups of the PECH segment as initiating sites resulted in the formation of (PECH-b-St)-g-PMMA). The structures of the intermediate polymers at various stages were characterized by … |
| Anahtar Kelimeler |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 27 |
| Scopus | 27 |
| Google Scholar | 37 |