Photochemically masked benzophenone Photoinitiated free radical polymerization by using benzodioxinone
Yazarlar (4)
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Polymer | ||
| Dergi ISSN | 0032-3861 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 10-2006 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-10-2006 |
| Cilt / Sayı / Sayfa | 47 / 22 / 7611–7614 | DOI | 10.1016/j.polymer.2006.09.020 |
| Makale Linki | http://linkinghub.elsevier.com/retrieve/pii/S0032386106010743 | ||
| Özet |
| A new photoinitiating system for free radical polymerization of methyl methacrylate (MMA) is reported. This system consists of benzodioxinone and hydrogen donors such as triethylamine (TEA), N,N-dimethyl ethanol amine (DMEA) and tetrahydrofuran (THF). A feasible mechanism involves photoinduced formation of benzophenone from benzodioxinone and subsequent hydrogen abstraction of photoexcited benzophenone from hydrogen donors to yield radicals capable of initiating polymerization of MMA. (c) 2006 Elsevier Ltd. All rights reserved. |
| Anahtar Kelimeler |
| photolysis | polymerization | benzodioxinone |
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