Clay PMMA Nanocomposites by Photoinitiated Radical Polymerization Using Intercalated Phenacyl Pyridinium Salt Initiators
Yazarlar (5)
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Macromolecular Chemistry and Physics | ||
| Dergi ISSN | 1022-1352 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 05-2006 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 18-04-2006 |
| Cilt / Sayı / Sayfa | 207 / 9 / 820–826 | DOI | 10.1002/macp.200500511 |
| Makale Linki | http://doi.wiley.com/10.1002/macp.200500511 | ||
| Özet |
| In situ synthesis of poly(methyl methacrylate) (PMMA) nanocomposites by photopolymerization using organophilic, montmorillonite (MMT) as the layered clay is reported. MMT clay was ion exchanged with N-phenacyl, N,N-dimethylanilinium hexafluoro phosphate (PDA) which acts as both suitable intercalant- and photo-initiator. These modified clays were then dispersed in methyl methacrylate (MMA) monomer in different loading degrees to carry out the in situ photopolymerization. Intercalation ability of the photoinitiator and exfoliated nanocomposite structure were evidenced by both X-ray diffraction (XRD) spectroscopy and transmission electron microscopy (TEM). Thermal properties and morphologies of the resultant nanocomposites were also studied. |
| Anahtar Kelimeler |
| montmorillonite | nanocomposites | phenacyl pyridinium salt | photopolymerization | poly(methyl methacrylate) |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları |