Facile synthesis of silicon carbide/hydroxyapatite composites through ball-mill for enhancing adsorption of tetracycline
    
Yazarlar (4)
Serkan Başlayıcı İstanbul Medipol Üniversitesi, Türkiye
Buket Gulen Yalova Üniversitesi, Türkiye
Doç. Dr. Mehmet BUĞDAYCI Yalova Üniversitesi, Türkiye
Pelin Demircivi Yalova Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı International Journal of Environmental Analytical Chemistry (Q3)
Dergi ISSN 0306-7319 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 07-2023
Cilt / Sayı / Sayfa 104 / 20 / 9275–9293 DOI 10.1080/03067319.2023.2229737
Makale Linki https://www.tandfonline.com/doi/full/10.1080/03067319.2023.2229737
Özet
Tetracycline adsorption from aqueous solution was investigated using silicon carbide/hydroxyapatite (SiC/HA), which is a novel adsorbent used for the first time in this study. Batch adsorption experiments were conducted to identify the effects of adsorbent amount, contact time, solution pH and temperature. The maximum adsorption capacity was found to be 5.88 mg g−1 for 60/40 ratio, while raw SiC and HA samples exhibited lower capacities for tetracycline adsorption (2.11 mg g−1 and 3.50 mg g−1). Maximum adsorption capacity was obtained at pH 7 with qe = 2,16 mg g−1. Langmuir and Freundlich isotherm models were used to analyse experimental data and the results showed that monolayer tetracycline adsorption occurred on SiC/HA surface, which leaded Langmuir isotherm model with maximum adsorption capacity of 45.87 mg g−1. Kinetic studies were performed at different time intervals and experimental data were analysed by pseudo-first order and pseudo-second order kinetic model. The pseudo second-order kinetic model defined the experimental data better than the others (R2 = 0.99). Moreover, thermodynamic studies revealed that TC adsorption was an endothermic process with spontaneous nature and feasible.
Anahtar Kelimeler
adsorption | hydroxyapatite | Silicon carbide | tetracycline