Promoting photo-fenton catalytic performance of novel NiZrO3-type perovskite: Optimization with response surface methodology

KANMAZ KELEŞOĞLU, Nergiz Zeynep; BUĞDAYCI, Mehmet

doi:10.1016/j.molstruc.2023.136718

Promoting photo-fenton catalytic performance of novel NiZrO3-type perovskite: Optimization with response surface methodology

Yazarlar (2)

Arş. Gör. Dr. Nergiz Zeynep KANMAZ KELEŞOĞLU Yalova Üniversitesi, Türkiye

Doç. Dr. Mehmet BUĞDAYCI Yalova Üniversitesi, Türkiye

Makale Türü	Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı	Journal of Molecular Structure (Q2)
Dergi ISSN	0022-2860 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler	SCI-Expanded
Makale Dili	İngilizce	Basım Tarihi	01-2024
Cilt / Sayı / Sayfa	1295 / 1 / 136718–	DOI	10.1016/j.molstruc.2023.136718
Makale Linki	http://dx.doi.org/10.1016/j.molstruc.2023.136718

Özet

Perovskite type NiZrO3 photocatalysts were synthesized by ball-mill technique and used for tetracycline (TC) degradation. NiZrO3 milled for 6 h (NiZrO3-6h) had significant-99 % photo-Fenton catalytic activity on TC removal It was determined that the characteristic peaks of NiZrO3 with XRD, spherical shaped structures with SEM, no organic peaks in the structure with FTIR, band gap of 4.40 eV with DRS and stable colloids with zeta potential. Response surface methodology (RSM) including Box-Behnken design (BBD) was applied to examine H2O2, Fe²⁺ and initial TC concentration effects on degradation and it was observed that H2O2 concentration had the highest effect on TC degradation. The photocatalytic efficacy of NiZrO3 could still eliminate 78 % of initial antibiotic molecules after eight-cycle. The application potential for Photo-Fenton assisted NiZrO3-6h was also observed in the degradation of other organic pollutants such as drugs (salicylic acid, ciprofloxacin, ampicillin) and dye (methylene blue, rhodamine-b, orange-II, malachite green, crystal violet). It suggests that the mechanochemically synthesized NiZrO3-6h perovskite could be suitable for its effective use in the photo-Fenton catalytic system.

Anahtar Kelimeler

Science Direct

BM Sürdürülebilir Kalkınma Amaçları

Atıf Sayıları
SCOPUS	16
Google Scholar	20

Promoting photo-fenton catalytic performance of novel NiZrO3-type perovskite: Optimization with response surface methodology

Dergi Adı	Journal of Molecular Structure
Yayıncı	Elsevier B.V.
Açık Erişim	Hayır
ISSN	0022-2860
E-ISSN	1872-8014
CiteScore	8,0
SJR	0,628
SNIP	0,999

Promoting photo-fenton catalytic performance of novel NiZrO3-type perovskite: Optimization with response surface methodology

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