Production and characterization of Ti-doped SrAl2O4 via volume combustion synthesis: application for dye removal
     
Yazarlar (2)
Pelin Demircivi Yalova Üniversitesi, Türkiye
Doç. Dr. Mehmet BUĞDAYCI Yalova Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Desalination and Water Treatment
Dergi ISSN 1944-3994 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 03-2020
Cilt / Sayı / Sayfa 181 / 1 / 412–421 DOI 10.5004/dwt.2020.25114
Özet
Titanium-doped strontium aluminate (Ti-SrAl2 O4 ) composites were synthesized by volume combustion synthesis using various Ti amounts (0–20 wt.%). The composites were characterized by X-ray diffraction (XRD), scanning electron microscope and energy dispersive spectrometer analysis. XRD results showed that SrO-Sr phases, which are the residues of SrAl2 O4 production, were elim-inated after doping with Ti. The adsorption capacities of the composite samples were examined using Orange II dye in batch system for several parameters such as Ti loading amount, solution pH, contact time and temperature. Freundlich adsorption isotherm model was the best-suited model to describe the isotherm data and the maximum adsorption capacity was found to be 136.99 mg g–1 at natural pH level. In acidic medium, the highest Orange II adsorption (80%) was observed, while in basic medium the adsorption of Orange II decreased to 64%. This study showed that Ti-SrAl2 O4 could be used as an adsorbent with high adsorption capacity for removal of Orange II dye. Three-factor three-level Box–Behnken experimental design with response surface modeling was applied for statistical analysis of the experiments. Ti amount (0%–20%), solution pH (2–12) and temperature (298–318 K) were chosen as independent variables, while Orange II adsorption capacity indicated the response. Analysis of variance was used to examine the significance of independent variables and their interactions.
Anahtar Kelimeler
Adsorption | Box–Behnken experimental design | Orange II | Ti-doped SrAl2 O4 | Volume combustion synthesis