Influence of TiO2 nanofillers on the dielectric response of proton conducting sulfonated polyether ether ketone/ionic liquid electrolytes
Yazarlar (3)
Doç. Dr. Hikmet OKKAY Yalova Üniversitesi, Türkiye
Ufuk Abacı Kocaeli Üniversitesi, Türkiye
Doç. Dr. Mesut YILMAZOĞLU Yalova Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Composites Communications (Q1)
Dergi ISSN 2452-2139 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 08-2025
Kabul Tarihi Yayınlanma Tarihi 01-08-2025
Cilt / Sayı / Sayfa 57 / 1 / 102466–0 DOI 10.1016/j.coco.2025.102466
Makale Linki https://doi.org/10.1016/j.coco.2025.102466
Özet
The impacts of titanium dioxide (TiO2) filler on the dielectric response of ionic liquid (IL)-doped sulfonated polyether ether ketone (SPEEK) electrolytes have been investigated. Neat SPEEK, IL-doped SPEEK (SPIL), and IL-doped TiO2-filled SPEEK (SPILTO) composite membranes were prepared with the conventional solution cast method and characterized by various techniques. Fourier-transform infrared (FTIR) spectroscopy analyses confirmed the sulfonation and also showed the dispersion of imidazole and TiO2. Thermogravimetric analysis (TGA) results showed that all composites are thermally stable to comply with electrochemical requirements up to nearly 150 °C. SPILTO-1 composite exhibited a storage modulus of 74 MPa and a glass transition temperature (Tg) of 140 °C. More than 1 wt% TiO2 fillers resulted in heterogeneous membrane surfaces for SPILTO samples. The SPILTO-1 electrolyte showed a …
Anahtar Kelimeler
Dielectric polarization | Ionic liquid | Relaxation time | SPEEK | TiO2