Plasticizer effect on dielectric properties of poly(methyl methacrylate)/titanium dioxide composites
     
Yazarlar (3)
Ufuk Abacı Kocaeli Üniversitesi, Türkiye
H Yuksel Guney Kocaeli Üniversitesi, Türkiye
Doç. Dr. Mesut YILMAZOĞLU Yalova Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Polymers and Polymer Composites (Q2)
Dergi ISSN 0967-3911 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 11-2021
Cilt / Sayı / Sayfa 29 / 9 / – DOI 10.1177/09673911211014757
Makale Linki http://dx.doi.org/10.1177/09673911211014757
Özet
The effect of plasticizer on dielectric properties of poly(methyl methacrylate) (PMMA)/titanium dioxide (TiO2) composites was investigated. Propylene carbonate (PC) was used as plasticizer in the samples which were prepared with the conventional solvent casting technique. Scanning Electron Microscopy with Energy Dispersive X-Ray Analysis (SEM-EDX) and Differential scanning calorimetry (DSC) analyses and LCR Meter measurements (performed between 300 K and 400 K), were conducted to examine the properties of the composites. With the addition of plasticizer, the thermal properties have changed and the dielectric constant of the composite has increased significantly. The glass transition temperature of pure PMMA measured 121.7°C and this value did not change significantly with the addition of TiO2, however, 112°C was measured in the sample with the addition 4 ml of PC. While the dielectric constant of pure PMMA was 3.64, the ε′ value increased to 5.66 with the addition of TiO2 and reached 12.6 with the addition of 4 ml PC. These changes have been attributed to increase in amorphous ratio that facilitates polymer dipolar and segmental mobility.
Anahtar Kelimeler
Dielectric spectroscopy | PMMA | TiO2 | polymer composite | thermal properties